Last week's show is here: http://prowresblog.blogspot.com/2013/09/wwe-main-event-942013-results-and-review.html
Antonio Cesaro vs. Kofi Kingston
These two always match up well so this should be quite good.
The Prime Time Players vs. 3MB
This one might be good. 3MB needs to bump around a lot and the faces need to toss them to make this work.
R-Truth vs. Big E Langston
Overall thoughts: Cesaro/Kofi was great and the big highlight here. Don't miss that match. The tag was fine too so overall it was a good episode of main event.